Champions League Betting Predictions & Odds: Week 3 (21-22 October)

We are back with yet another set of Champions League betting predictions! The UEFA’s prestigious tournament is closing out Week 3 of the matchdays. We can see the best teams across Europe facing off against each other, with underdogs also seeking to climb the ladder. Thus, we will provide you with odds and a brief analysis of the best bets available!

We are ahead of yet another match-week. Thus, we have researched the best markets this week to compile our Champions League betting predictions, with the odds attached. Top clubs are entering crucial phases of their campaigns, where one win can change the entire group dynamic. With intense rivalries and surprise contenders emerging, bettors have plenty to analyze before placing their wagers. But we are sparing you from the analytics, with our quick summary and tips! Of course, if you are a beginner bettor, this is also an ideal time for you to jump into the action. For now, there are plenty of fixtures where the balance between teams and their skills is different. However, after a few months, the best teams will face off against each other, where the proposion bets seem to be better options than an outright bet. Register at any of the online sportsbook sites in Germany to bet on the upcoming UEFA Champions League games!

Info – UEFA Champions League Betting Predictions for Week 3

The UEFA Champions League stands as Europe’s most prestigious club tournament. With the best teams in competition, it is one of the most-viewed soccer events all across the world! According to the UEFA, we have a total of 18 games happening in the coming two days, 9 fixtures for each day. Each day, the earliest game starts at 18:45 (CET).

This is followed by a prime-time slate that promises intense battles across Europe. The third week of the group stage often serves as a turning point, separating early frontrunners from those struggling to keep pace. This is where strategies sharpen and every point matters. Bettors should pay attention to how teams adapt their tactics, especially those playing away from home or facing back-to-back tough opponents. Register at bet365 Sportsbook and place a bet on the highlighted odds!

UEFA Champions League Betting Odds For October 21, 2025

Let’s start our Champions League betting predictions in chronological order. The October 21 fixtures come with some of the most prestigious teams in the competition. Arsenal will likely beat Atletico Madric, and join the higher competition as usual. Dortmund facing off against Copenhagen is yet another easy bet which we highly recommend for beginner bettors. Perhaps one of the tightest games will be held between PSV and Napoli, where the skills are quite unpredictable. But if you are looking for a more secure bets, then the Milan vs Gilloise, and the Villarreal vs Man City games are the best options.

Outright Match Winners

• Barcelona (1.20) Draw (6.50) Olympiakos (13.00)
• Kairat Almaty (2.75) Draw (3.10) Pafos FC (2.62)
• Arsenal (1.60) Draw (4.10) Atletico Madrid (5.25)
• Bayer Leverkusen (4.75) Draw (3.90) PSG (1.66)
• FC Copenhagen (4.00) Draw (3.60) Borussia Dortmund (1.90)
• Newcastle (1.57) Draw (4.20) Benfica (5.50)
• PSV (3.10) Draw (3.50) Napoli (2.25)
• Union Saint Gilloise (5.00) Draw (3.90) Inter Milan (1.70)
• Villarreal (4.33) Draw (4.00) Man City (1.72)

Dortmund vs Copenhagen Goals

• Above 2.5 (1.80)
• Under (2.00)

Leverkusen vs PSG results

• First Half: Bayer (4.75) Draw (2.50) PSG (2.20)
• Second Half: Bayer (4.33) Draw (2.75) PSG (1.95)
• 10 Minutes: Bayer (9.00) Draw (1.20) PSG (5.50)

UEFA Champions League Fixtures and Betting Odds (October 22-23, 2025)

Now, let’s see our Champions League betting predictions for the second day during this week. The second day starts with Athletic Bilbao facing off against Qarabag, with a clear home-advantage. Galatasaray will face off against Glimt. It is clear that this section of the market has some of the more exciting games, such as the Liverpool-Frankfurt pairing. However, all eyes are on Madrid and Juventus! For old-school fans, Madrid’s dominance at home is the expected outcome. Finally, the match-day closes out with a great, tension-cooling game between Sporting and Marseille.

Outright Odds:

• Athletic Bilbao (1.30) Draw (5.25) FK Qarabag (10.00)
• Galatasaray (1.55) Draw (4.50) Bodo/Glimt (5.00)
• Atalanta (1.45) Draw (4.75) Slavia Prague (6.00)
• Bayern München (1.20) Draw (6.50) Club Brugge (13.00)
• Chelsea (1.22) Draw (7.00) Ajax (11.00)
• Eintracht Frankfurt (5.00) Draw (4.50) Liverpool (1.57)
• Monaco (3.00) Draw (3.50) Tottenham (2.30)
• Real Madrid (1.48) Draw (4.50) Juventus (6.00)
• Sporting (2.20) Draw (3.70) Marseille (3.00)

Madrid vs Juventus Goals Scored By

• Kylian Mbappe (1.61)
• Jonathan David (3.10)

Maximizing Your Bets With Our Champions League Betting Predictions!

Placing a bet on the Champions League is straightforward once you find a trusted sportsbook. After registering and verifying your identity, head to the football section and locate the Champions League markets. Choose the fixture, select the market that fits your prediction, and confirm your slip.

Watching matches live is not only effective for an insight on the performance, but also a great way to join the live-betting market. Epecially in a competition known for late goals and sudden momentum shifts. Explore different markets such as outright winners, goal totals, or player-specific bets to fully be a part of this month’s UEFA action! Register at bet365 Sportsbook and browse the best markets for the UEFA Champions League!

Click here to try the best odds at bet365 Sportsbook!